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111-69-3

Name 1,4-Dicyanobutane
CAS 111-69-3
EINECS(EC#) 203-896-3
Molecular Formula C6H8N2
MDL Number MFCD00001975
Molecular Weight 108.14
MOL File 111-69-3.mol

Chemical Properties

Appearance Adiponitrile is a combustible, water-white to yellow, oily liquid. A solid below 1.1 C. Practically odorless
Melting point  1-3 °C (lit.)
Boiling point  295 °C (lit.)
density  0.951 g/mL at 25 °C(lit.)
vapor density  3.7 (vs air)
vapor pressure  0.01 mm Hg ( 40 °C)
refractive index  n20/D 1.438(lit.)
Fp  163 °C
storage temp.  Store below +30°C.
solubility  50g/l
form  Liquid
color  Clear colorless to slightly yellow
Specific Gravity 0.951
explosive limit 7-14%(V)
Water Solubility  90 g/L (20 ºC)
FreezingPoint  1℃
BRN  1740005
Dielectric constant 32.5(Ambient)
Exposure limits TLV-TWA 18 mg/m3 (4 ppm) (NIOSH).
CAS DataBase Reference 111-69-3(CAS DataBase Reference)
NIST Chemistry Reference Hexanedinitrile(111-69-3)
EPA Substance Registry System 111-69-3(EPA Substance)

Safety Data

Hazard Codes  T
Risk Statements 
R25:Toxic if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R36/38:Irritating to eyes and skin .
R23/25:Toxic by inhalation and if swallowed .
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S39:Wear eye/face protection .
RIDADR  UN 2205 6.1/PG 3
WGK Germany  1
RTECS  AV2625000
Autoignition Temperature 460 °C
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29269090
Safety Profile
Poison by inhalation, ingestion, subcutaneous, and intraperitoneal routes. The nitrile group wdl behave as a cyanide when ingested or absorbed in the body. It produces disturbances of the respiration and circulation, irritation of the stomach and intestines, and loss of weight. Its low vapor pressure at room temperature makes exposure to harmful concentrations of its vapors unlikely if handled with Flammable when exposed to heat or flame. When heated to decomposition it emits toxic fumes of CN-. Can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. See also HYDROCYANIC ACID and NITRILESreasonable care in well-venulated areas.
Hazardous Substances Data 111-69-3(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 138 mg/kg LD50 dermal Rabbit 2134 mg/kg

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