General Description
Colorless or white colored needles that turn red or purple in air. Melting point 64-66 C. Density 1.14 g/cm3. Flash point 280 F. May irritate skin and eyes. Toxic by skin absorption, inhalation or ingestion. Used in aramid fiber manufacture, as a polymer additive, dye manufacturing, as a laboratory reagent, and in photography.
Reactivity Profile
1,3-PHENYLENEDIAMINE(108-45-2) an aromatic amine, neutralizes acids, acid chlorides, acid anhydrides and chloroformates in exothermic reactions to form salts. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Incompatible with oxidizing agents .
Air & Water Reactions
Soluble in water [Merck].
Potential Exposure
Used in making various dyes; as a curing agent for epoxy resin; rubber, textile fibers; urethanes, corrosion inhibitors; adhesives; in photographic and analytical procedures and processes.
Fire Hazard
This chemical is combustible. Dust may form explosive mixtures in air
First aid
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
Shipping
UN1673 Phenylenediamines (o-, m-, p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Incompatibilities
Dust may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, acid chlorides; acid anhydrides; chloroformates. Heat and light contribute to instability. Keep away from metals.
Chemical Properties
Grey crystal granule
Chemical Properties
m-Phenylenediamine is a colorless to white crystalline substance that turns red upon exposure to air
Waste Disposal
Controlled incineration whereby oxides of nitrogen are removed from the effluent gas by scrubber, catalytic or thermal device.
Uses
1,3-Phenylenediamine is used in the foaming-type hair dye composition.
Uses
The appearance of the high purity of the m-phenylenediamine is snow white flake solid used as a synthetic electronic grade polyimide material and epoxy resin curing agent.
Definition
ChEBI: 1,3-phenylenediamine is a phenylenediamine taht is benzene substituted at positions 1 and 3 with amino functions.
Flammability and Explosibility
Nonflammable
Carcinogenicity
"Occupational exposure to m-PDA may occur through
inhalation and dermal contact with this compound at workplace
where m-PDA is produced or used. The general population may be exposed to m-PDA via dermal contact
with consumer products containing this compound."An IARC Working
Group concluded, on the basis of lack of human data and
inadequate animal data, that m-PDA was not classifiable
(Group 3) as to its carcinogenicity to humans.
Metabolic pathway
By the perfused rat liver, 1,3-diaminobenzene (MPD)
is metabolized to three identified N-acetylated
derivatives N-acetyl-1,3-diaminobenzene, N,N'-
diacetyl-1,3-diaminobenzene, and N,N'-diacetyl-2,4-
diaminophenol which are identical to the metabolites
excreted in rat urine.
Purification Methods
Purify the diamine by distillation under a vacuum followed by recrystallisation from EtOH (rhombs) and if necessary redistillation. It should be protected from light; otherwise it darkens rapidly. [Neilson et al. J Chem Soc 371 1962, IR: Katritzky & Jones J Chem Soc 3674, 2058 1959, UV: Forbes & Leckie Can J Chem 36 1371 1958.] The hydrochloride has m 277-278o, and the bis-4-chlorobenzenesulfonyl derivative has m 220-221o from H2O (214-215o, from MeOH/H2O) [Runge & Pfeiffer Chem Ber 90 1737 1957]. The acetate has m 191o. [Beilstein 13 IV 79.]
