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103-33-3

Name AZOBENZENE
CAS 103-33-3
EINECS(EC#) 203-102-5
Molecular Formula C12H10N2
MDL Number MFCD00003022
Molecular Weight 182.22
MOL File 103-33-3.mol

Chemical Properties

Appearance Azobenzene is a combustible, orange-red crystalline solid.
Melting point  65-68 °C (lit.)
Boiling point  293 °C (lit.)
density  1.09 g/mL at 25 °C(lit.)
vapor pressure  1 mm Hg ( 104 °C)
refractive index  1.62662 (78.1℃)
Fp  100 °C
storage temp.  2-8°C
solubility  6.4mg/l
form  Crystalline Powder
color  Orange
Stability: Stable. Combustible. Incompatible with strong oxidizing agents. Air and light sensitive.
Water Solubility  Soluble in alcohol, ether, benzene and glacial acetic acid. Insoluble in water.
Merck  14,917
BRN  1819138
CAS DataBase Reference 103-33-3(CAS DataBase Reference)
IARC 3 (Vol. 8, Sup 7) 1987
EPA Substance Registry System Azobenzene (103-33-3)

Safety Data

Hazard Codes  T,N,Xn,F
Risk Statements 
R45:May cause cancer.
R20/22:Harmful by inhalation and if swallowed .
R48/22:Harmful: danger of serious damage to health by prolonged exposure if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R68:Possible risk of irreversible effects.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R62:Possible risk of impaired fertility.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R38:Irritating to the skin.
R11:Highly Flammable.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
Safety Statements 
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S36/37:Wear suitable protective clothing and gloves .
S33:Take precautionary measures against static discharges .
S29:Do not empty into drains .
S16:Keep away from sources of ignition-No smoking .
S9:Keep container in a well-ventilated place .
S7:Keep container tightly closed .
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  CN1400000
Autoignition Temperature 890 °F
TSCA  Yes
HazardClass  6.1(b)
PackingGroup  III
HS Code  29270000
Safety Profile
Moderately toxic by ingestion and possibly other routes. Questionable carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. When heated to decomposition it emits toxic fumes of NOx.
Hazardous Substances Data 103-33-3(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 1000 mg/kg

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