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100-46-9

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Identification

Name
Benzylamine
CAS
100-46-9
Synonyms
A-AMINOTOLUENE
AKOS BBS-00003631
ALPHA-AMINOTOLUENE
BENZENEMETHANAMINE
BENZENMETHANAMINE
BENZYLAMINE
BZA
HISTOPREP FROZEN TISSUE EMBEDDING MEDIA
LABOTEST-BB LTBB000422
N-BENZYLAMINE
PHENYLMETHYLAMINE
RARECHEM AL BW 0006
TISSUEPREP EMBEDDING MEDIA
(aminomethyl)benzene
(phenylmethyl)amine[qr]
alpha-aminotoluene[qr]
Aminotoluene
-Aminotoluene
aminotoluene[qr]
benzenemethanamine[qr]
EINECS(EC#)
202-854-1
Molecular Formula
C7H9N
MDL Number
MFCD00212756
Molecular Weight
107.15
MOL File
100-46-9.mol

Chemical Properties

Appearance
colourless liquid with an ammoniacal odour
mp 
-30 °C
bp 
184-185 °C(lit.)

density 
0.981 g/mL at 25 °C(lit.)

refractive index 
n20/D 1.543(lit.)

Fp 
140 °F

Stability:
Stability Combustible. Incompatible with strong oxidizing agents, strong acids.
Water Solubility 
soluble
Sensitive 
Air Sensitive
Merck 
14,1125
BRN 
741984
Uses
Chemical intermediate for dyes, pharmaceuticals, and polymers.
CAS DataBase Reference
100-46-9(CAS DataBase Reference)
NIST Chemistry Reference
Benzylamine(100-46-9)
EPA Substance Registry System
100-46-9(EPA Substance)

Safety Data

Hazard Codes 
C
Risk Statements 
R21/22:Harmful in contact with skin and if swallowed .
R34:Causes burns.
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
RIDADR 
UN 2735 8/PG 2

WGK Germany 
1

RTECS 
DP1488500


34
HazardClass 
8
PackingGroup 
II
HS Code 
29214900
Hazardous Substances Data
100-46-9(Hazardous Substances Data)

Raw materials And Preparation Products

Raw materials
Ammonium hydroxide-->Benzyl chloride-->Benzaldehyde-->Ammonium bicarbonate-->Hexamethylenetetramine-->O-Phthalimide
Preparation Products
(R)-3-(Boc-amino)pyrrolidine-->1-Boc-3-(Aminomethyl)azetidine-->(S)-3-Hydroxypyrrolidine hydrochloride-->NAPROANILIDE-->Admire-->(S)-1-Benzyl-3-pyrrolidinol -->4-N-Boc-4-N-Methyl-aminopiperidine-->(R)-(+)-1-Benzyl-3-pyrrolidinol-->(+)-(3R,4R)-BIS(DIPHENYLPHOSPHINO)-1-BENZYLPYRROLIDINE-->4-Dimethylaminobenzaldehyde-->(3S,4S)-(-)-1-BENZYL-3,4-BIS(DIPHENYLPHOSPHINO)PYRROLIDINE-->1-N-Boc-3-Azetidinecarboxylic acid-->1-((6-Chloro-3-pyridinyl)methyl)-N-nitro-imidazolidinimine-->Mafenide hydrochloride-->N-BOC-3-AMINOOXETANE-3-CARBOXYLIC ACID-->1-BENZYL-3-METHYL-4-PIPERIDONE-->(R)-3-Hydroxypyrrolidine-->ETHYL 4-PIPERIDONE-3-CARBOXYLATE HYDROCHLORIDE-->N-Benzyl-4-piperidone-->METHYL 3-AMINOOXETANE-3-CARBOXYLATE-->DL-Aspartic acid-->2,6-Dimethylpiperazine-->1-BENZYL-4-HYDROXY-4-(3-TRIFLUOROTOLYL)PIPERIDINOL-->N,N-Dimethylbenzylamine-->Methyl 1-benzyl-4-oxo-3-piperidine-carboxylate hydrochloride-->3-Butyl-2-[[4-[2-(2H-tetrazol-5-yl)phenyl]phenyl]methyl]-2,4-diazaspiro[4.4]non-3-en-1-one-->6-benzylaminopurine-->4-(1-BENZYLPIPERIDIN-4-YLOXY)-3,5-DICHLOROBENZENAMINE-->4-((4-BENZYLMORPHOLIN-2-YL)METHOXY)-3,5-DICHLOROBENZENAMINE-->trans-1,4-Diaminocyclohexane-->6-BENZYLAMINOPURINE-->N'-BENZYL-N,N-DIMETHYLETHYLENEDIAMINE-->N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine-->sodium dibenzyl amine enzene sulfonate-->BENZYL-(2-METHYLSULFANYL-PYRIMIDIN-4-YL)-AMINE-->4-(AMINOMETHYL)BENZENESULFONAMIDE-->Ethyl 3-(benzylamino)propanoate-->3-Aminopyrrolidine-->N-BENZYLIMINODIACETIC ACID

Hazard Information

General Description
Colorless to light yellow liquid with a strong odor of ammonia. Floats and mixes with water.
Reactivity Profile
In presence of moisture, BENZYLAMINE(100-46-9) may weakly corrode some metals. Liquid will attack some plastics [USCG, 1999]. Neutralize acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides.
Air & Water Reactions
Water soluble.
Hazard
Highly toxic, strong irritant to skin and mucous membranes.
Health Hazard
Inhalation of vapor causes irritation of the mucous membranes of the nose and throat, and lung irritation with respiratory distress and cough. Headache, nausea, faintness, and anxiety can occur. Exposure to vapor produces eye irritation with lachrymation, conjunctivitis, and corneal edema resulting in halos around lights. Direct local contact with liquid is known to produce severe and sometimes permanent eye damage and skin burns. Vapors may also produce primary skin irritation and dermatitis.
Fire Hazard
Special Hazards of Combustion Products: Toxic nitrogen oxides may form in a fire.

Material Safety Data Sheet(MSDS)

msds information
benzylamine(100-46-9).msds

Spectrum Detail

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