Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Lithium chloride(7447-41-8)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Lithium chloride
CAS
7447-41-8
Formula
ClLi
Formula
LiCl
Molecular Weight
42.39
EINECS
231-212-3
RTECS
OJ5950000
RTECS Class
Tumorigen; Drug; Mutagen; Reproductive Effector; Human Data; Primary Irritant
Merck
13,5550
Beilstein/Gmelin
13672 (G)
EC Class
harmful, irritant

Physical and Chemical Properties

Appearance
White crystals, granules or crystalline powder, deliquescent.
Solubility in water
769 g/L
Melting Point
614
Boiling Point
1382
Vapor Pressure
360 (1235 C)
Density
2.07 g/cm3
Heat Of Vaporization
Usage
Manufacture mineral waters, in pyrotechnics, soldering aluminum, in refrigerating machines.

First Aid Measures

Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get on skin or in eyes. Do not ingest or inhale. Discard contaminated shoes.

Hazards Identification

Inhalation
May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation.
Skin
May cause severe irritation and possible burns. Chronic ingestion may cause dizziness, ringing in the ears, visual disturbances, tremors, and mental confusion. Prolonged absorption may affect electrolyte balance and impair kidney function. Dehydration, weight loss, skin effects, and thyroid disturbances have been reported.
Eyes
Contact with eyes may cause severe irritation, and possible eye burns.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause muscle tremor and impaired motor function. May cause circulatory system failure. May cause cardiac disturbances. May cause tremors and convulsions. May cause central nervous system effects.
EC Risk Phrase
R 22 36/37/38
EC Safety Phrase
S 26 36/37/39

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
Chronic ingestion may cause dizziness, ringing in the ears, visual disturbances, tremors, and mental confusion. Prolonged absorption may affect electrolyte balance and impair kidney function. Dehydration, weight loss, skin effects, and thyroid disturbances have been reported.
Poison Class
3

Fire Fighting Measures

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible. Extinguishing media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Fire Potential
This material is probably combustible.

Accidental Release Measures

Small spills/leaks
Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code
14
Incompatibilities
Bromine trifluoride, strong acids.
Stability
Stable under normal temperatures and pressures.
Decomposition
Hydrogen chloride, chlorine, irritating and toxic fumes and gases.

Transport Information

HS Code
2827 39 80
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