Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Zinc peroxide (1314-22-3)

Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Zinc peroxide
Synonyms
Zinc dioxide
Zinc superoxide
CAS
1314-22-3
Formula
O2Zn
Molecular Weight
97.37
EINECS
215-226-7
RTECS
ZH4865000
Merck
12,10282
Beilstein/Gmelin
107267 (G)

Physical and Chemical Properties

Appearance
A white powder.
Solubility in water
Decomposes
Melting Point
212
Density
1.57 g/cm3 (20 C)
Usage
In pharmaceuticals, accelerator in rubber compounding, curing agent for synthetic elastomers.

First Aid Measures

Ingestion
Seek medical assistance.
Inhalation
Aspirated zinc stearate may cause severe respiratory irritation.
Skin
Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists.
Eyes
Immediately flush skin or eyes with running water for at least 20 minutes.

Handling and Storage

Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Ingestion
Serious gi complications have resulted from the ingestion of concentrated solutions and enemas with dilute peroxide solutions.
Inhalation
Inhalation of vapors from concentrated (greater than 10%) solutions may result in severe pulmonary irritation. Interstitial lung disease and respiratory arrest have also been reported following massive exposures.
Skin
Dermal exposure to dilute (3%) solutions generally results in a bleaching of the affected area in association with a tingling sensation and lasts 2 to 3 hours, if washed promptly after contact.
Eyes
See Inhalation.
Hazards
May explode from friction, heat or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). Some will react explosively with hydrocarbons (fuels). Containers may explode when heated. Runoff may create fire or explosion hazard.
UN (DOT)
1516

Exposure Controls/Personal Protection

Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Poison Class
3

Fire Fighting Measures

Fire Fighting
Flood with water. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible.
Fire Potential
May explode from friction, heat or contamination. These substances will accelerate burning when involved in a fire.

Accidental Release Measures

Small spills/leaks
Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers.

Stability and Reactivity

Incompatibilities
Mixtures with combustible material can sometimes be ignited by friction or contact with moisture Mixtures with aluminum or zinc powder burn brilliantly.
Stability
No data.
Combustion Products
Fire may produce irritating and/or toxic gases.

Transport Information

UN Number
1516
Hazard Class
5.1
Packing Group
II