Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity
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Tris(2-chloroethyl) phosphate(115-96-8)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity

Product Identification

Product Name
Tris(2-chloroethyl) phosphate
Synonyms
Amgard TCEP
Celluflex
Disflamoll TCA
Ethanol, 2-chloro-, phosphate (3:1)
Niax Flame Retardant 3CF
Tris(2-chloroethyl) orthophosphate
CAS
115-96-8
Formula
C6H12Cl3O4P
Molecular Weight
285.5
EINECS
204-118-5
RTECS
KK2450000
RTECS Class
Tumorigen; Mutagen; Reproductive Effector
Beilstein/Gmelin
1710938
Beilstein Reference
4-01-00-01379
EC Index Number
015-102-00-0
EC Class
Carcinogenic Category 3; Harmful; Dangerous for the Environment

Physical and Chemical Properties

Appearance
Odorless clear liquid.
Solubility in water
7 g/L
Boiling Point
330
Vapor Pressure
.06
Density
1.422 g/cm3
Partition Coefficient
1.44
Heat Of Vaporization
36.84 kJ/mol
Usage
Flame-retardant plasticizer.
Vapor Density
9.8
Refractive Index
1.4708 (20 C)

First Aid Measures

Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.

Hazards Identification

Inhalation
May cause respiratory tract irritation.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
The toxological properties of this substance have not been fully investigated.
Poison Class
3

Fire Fighting Measures

Flash Point
232
Autoignition
480
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Containers may explode when heated. Extinguishing media: Cool containers with flooding quantities of water until well after fire is out. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Fire Potential
This chemical is combustible.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity

Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Incompatibilities
Strong oxidizing agents.
Decomposition
Hydrogen chloride, carbon monoxide, oxides of phosphorus, irritating and toxic fumes and gases, carbon dioxide.
Combustion Products
When heated to decomposition it emits very toxic fumes of phosphorous oxides and hydrogen chloride.
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