Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Capryl alcohol(111-87-5)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Capryl alcohol
Synonyms
Capryl alcohol
n-Caprylic alcohol
n-Octanol
n-Octyl alcohol
Octan-1-ol
CAS
111-87-5
Formula
C8H18O
Molecular Weight
130.22999999999999
EINECS
203-917-6
RTECS
RH6550000
RTECS Class
Mutagen; Natural Product; Primary Irritant
Merck
12,6849
Beilstein/Gmelin
1697461
Beilstein Reference
4-01-00-01756
EC Class
irritant

Physical and Chemical Properties

Appearance
Clear, oily liquid with a sweet, penetrating, aromatic odor.
Solubility in water
Insoluble
Melting Point
-16
Boiling Point
195
Vapor Pressure
0.02 (20 C)
Density
0.8246 g/cm3 (20 C)
Partition Coefficient
3
Heat Of Vaporization
41.04 kJ/mol
Heat Of Combustion
-5292 kJ/mol
Usage
Manufacture of perfumes and esters.
Saturation Concentration
85 ppm (0.008%) at 20 C; 104 ppm (0.01%) at 25 C (calculated)
Vapor Density
4.5
Odor threshold
0.49 ppm
Refractive Index
1.43 (20 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Inhalation
May cause respiratory tract irritation. May cause lung damage.
Skin
May cause mild skin irritation. May be absorbed through the skin.
Eyes
May cause eye irritation.
Ingestion
May cause digestive tract disturbances. Severe exposure to similar alcohols may cause various systemic effects including, digestive tract irritation, CNS depression, and heart, liver, and kidney abnormalities.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers.
EC Risk Phrase
R 36/37/38
EC Safety Phrase
S 26 36
UN (DOT)
1986

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Headache, dizziness, giddiness, ataxia, sedation and coma may occur.
Poison Class
4

Fire Fighting Measures

Flash Point
90
Autoignition
270
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: For small fires, use water spray, dry chemical, carbon dioxide or chemical foam.
Upper exp. limit
6.4
Lower exp. limit
.9
Fire Potential
Moderately flammable. Combustion with moderate heating.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.

Stability and Reactivity

Incompatibilities
Acids, acid chlorides, oxidizing agents.
Stability
Stable under normal temperatures and pressures.
Decomposition
Carbon monoxide, carbon dioxide.
Combustion Products
Fire will produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
1986
Hazard Class
3
Packing Group
I; II; III
HS Code
2905 16 80
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