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外観
白色～わずかにうすい褐色, 粉末
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溶解性
水に難溶。エタノール, アセトン, トルエンに可溶。エタノール及びアセトンに溶けやすく、水にほとんど溶けない。
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用途
有機合成原料、ゴムの加硫加速剤。
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用途
有機ゴム薬品(加硫促進剤)
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化学的特性
1,3-diphenylguanidine is a white or cream powder with a slight odour and bitter taste. slightly soluble in water, soluble in ethanol, chloroform, hot benzene, hot toluene, easily soluble in dilute inorganic acids. Used as medium speed accelerator for natural rubber and synthetic rubber, mainly used in the manufacture of tires, rubber plates, rubber shoes and other rubber industrial products.
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使用
1,3-Diphenylguanidine is used as pharmaceutical intermediate.
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定義
ChEBI: 1,3-diphenylguanidine is guanidine carrying a phenyl substituent on each of the two amino groups. It is used as an accelerator in the rubber industry. It has a role as an allergen.
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一般的な説明
White to cream-colored chalky powder. Bitter taste and slight odor.
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空気と水の反応
Sensitive to moisture. Aqueous solutions are strongly alkaline. Insoluble in water.
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反応プロフィール
1,3-Diphenylguanidine behaves as an amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. 1,3-Diphenylguanidine is incompatible with strong oxidizers.
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火災危険
1,3-Diphenylguanidine is combustible.
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接触アレルゲン
Diphenylguanidine is a rubber sensitizer that can induce immediate-type reactions and delayed-type contact allergy. It was formerly contained in “carba mix.” Occupational exposure concerns finished rubber items and the rubber manufacturing industry. The most frequent occupational categories are metal industry, homemakers, health services and laboratories, and the building industry.
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安全性プロファイル
Poison by ingestion and
intraperitoneal routes. Experimental
teratogenic and reproductive effects.
Mutation data reported. When heated to
decomposition it emits toxic fumes of NOx,.
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純化方法
1,3-Diphenylguanidine [102-06-7] M 211.3, m 148o, 10.12. Crystallise it from toluene,
