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外観
青緑色の結晶性粉末
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溶解性
水、エタノール及びアセトンに溶ける。
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解説
酢酸銅(Ⅱ)，密度1.88 g cm－3．融点115 ℃，沸点240 ℃．水に易溶，エタノール，エーテルに可溶．顔料，媒染剤，殺菌剤，有機反応の触媒などに用いられる．
森北出版「化学辞典（第2版）
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用途
触媒、媒染剤。
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ジンテーゼ
酸化銅(Ⅱ)，水酸化銅(Ⅱ)，炭酸水酸化銅(Ⅱ)などを酢酸に溶かし，濃縮すると暗緑青色の一水和物の結晶が得られる．
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説明
Copper (II) acetate, also referred to as cupric acetate, is the chemical compound with the formula Cu(OAc)22 where OAc- is acetate (CH3CO2-). The hydrated derivative, which contains one molecule of water for each Cu atom, is available commercially. Anhydrous Cu(OAc)2 is a dark green crystalline solid, whereas Cu2(OAc)4(H2O)2 is more bluish-green. Since ancient times, copper acetates of some form have been used as fungicides and green pigments. Today, copper acetates are used as reagents for the synthesis of various inorganic and organic compounds. Copper acetate, like all copper compounds, emits a blue-green glow in a flame.
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化学的特性
Cupric acetate is a greenish Blue powder or small crystals.
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来歴
Copper (II) acetate was historically prepared in vineyards, since acetic acid is a byproduct of fermentation. Copper sheets were alternately layered with fermented grape skins and dregs left over from wine production and exposed to air. This would leave a blue substance on the outside of the sheet. This was then scraped off and dissolved in water. The resulting solid was used as a pigment, or combined with arsenic trioxide to form copper acetoarsenite, a powerful insecticide and fungicide called Paris Green or Schweinfurt Green.
During the Second World War copper acetate was used as shark repellent . Under war conditions, before adoption it has been tested only very briefly (while in general successfully). The source says copper acetate does repel sharks in some situations but not in all.
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使用
Used as a catalyst or oxidizing agent in organic syntheses
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主な応用
The uses for copper (II) acetate are more plentiful as a catalyst or oxidizing agent in organic syntheses. For example, Cu2(OAc)4 is used to couple two terminal alkynes to make a 1,3-diyne:
Cu2(OAc)4 + 2 RC ≡ CH → 2 CuOAc + RC ≡ C-C ≡ CR + 2 HOAc
The reaction proceeds via the intermediacy of copper(I) acetylides, which are then oxidized by the copper(II) acetate, releasing the acetylide radical. A related reaction involving copper acetylides is the synthesis of ynamines, terminal alkynes with amine groups using Cu2(OAc)4.
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一般的な説明
A blue-green crystalline solid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Cupric acetate is used as an insecticide, in the preparation of other chemicals, as a fungicide, and mildew preventive.
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空気と水の反応
Water soluble.
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反応プロフィール
Salts, basic, such as Cupric acetate, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.
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健康ハザード
Inhalation of dust causes irritation of throat and lungs. Ingestion of large amounts causes violent vomiting and purging, intense pain, collapse, coma, convulsions, and paralysis. Contact with solutions irritates eyes; contact with solid causes severe eye surface injury and irritation of skin.
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火災危険
Special Hazards of Combustion Products: Irritating vapors of acetic acid may form in fires.
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安全性プロファイル
Poison by
subcutaneous and intraperitoneal routes.
Moderately toxic by ingestion.
Experimental reproductive effects. When
heated to decomposition it emits acrid
smoke and irritating fumes. See also
COPPER COMPOUNDS.
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職業ばく露
Cupric acetate is used as a fungicide, as a catalyst for organic reactions; in textile dyeing and as a pigment for ceramics.
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輸送方法
UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
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純化方法
Recystallise it twice from warm dilute acetic acid solutions (5mL/g) by cooling. [Beilstein 2 IV 111.]
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不和合性
Forms explosive materials with acetylene gas, ammonia, caustic solutions; sodium hypobromite; notromethane. Keep away from chemically active metals; strong acids; nitrates. Decomposes above 240C forming acetic acid fumes
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廃棄物の処理
Copper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill.
