4-ビニル-1-シクロヘキセン

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H225：引火性の高い液体および蒸気

  H304：飲み込んで気道に侵入すると生命に危険のおそ れ

  H315：皮膚刺激

  H351：発がんのおそれの疑い

  H361：生殖能または胎児への悪影響のおそれの疑い

  H412：長期的影響により水生生物に有害

• 注意書き

  P201：使用前に取扱説明書を入手すること。

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P273：環境への放出を避けること。

  P301+P310：飲み込んだ場合：直ちに医師に連絡すること。

  P303+P361+P353：皮膚（または髪）に付着した場合：直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。

  P331：無理に吐かせないこと。

4-ビニル-1-シクロヘキセン 価格

4-ビニル-1-シクロヘキセン 化学特性,用途語,生産方法

• 外観

  無色～ほとんど無色透明液体

• 用途

  エポキシ原料、溶剤、高分子原料

• 化学的特性

  4-Vinyl-1-cyclohexene, a cyclic alkene, is a highly flammable liquid.

• 使用

  Polymers, organic synthesis.

• 調製方法

  4-Vinylcyclohexene is produced by dimerization of butadiene, as a by-product of chlorination of butadiene, or frombutadiene on long storage.

• 一般的な説明

  Colorless liquid. Floats on water. Temperatures above 80F (26.6C) and prolonged exposure to oxygen-containing gases should be avoided because these conditions lead to discoloration and gum formation.

• 空気と水の反応

  Highly flammable. 4-Vinyl-1-cyclohexene oxidizes in air to form hydroperoxides. Slightly soluble in water.

• 反応プロフィール

  4-Vinyl-1-cyclohexene can react with oxidizing materials. 4-Vinyl-1-cyclohexene is also incompatible with peroxide catalysts. Prolonged exposure to oxygen-containing gases leads to discoloration and gum formation. .

• 健康ハザード

  Exposure can cause irritation of eyes, nose and throat. High concentrations have a narcotic effect.

• 安全性プロファイル

  Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion and inhalation. MilcU~7 toxic by skin contact. Experimental reproductive effects. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Can react with oxidizers. To fight fire, use foam, CO2, dry chemical.

• 職業ばく露

  4-Vinyl-1-cyclohexene is used as an intermediate for the production of vinylcyclohexene dioxide, which is used as a reactive diluent in epoxy resins. Previous uses of 4-vinyl-1-cyclohexene include comonomer in the polymerization of other monomers and for halogenation to polyhalogenated derivatives which are used as flame retardants.

• 発がん性

  A dose of 145 g/kg applied to mouse skin for 54 weeks provided weak evidence of carcinogenicity (109). Administration by gavage of doses of 0, 200, or 400 mg/kg body weight, 5 days per week, to groups of 50 F344/N rats for 103 weeks induced a slightly increased incidence of epithelial hyperplasia of the forestomach (1/50; 3/50; 5/47) and squamous cell papillomas or carcinomas (combined) of the skin, in males receiving the highest dose. Low-dose female rats whose survival was more similar to that of the vehicle controls had a marginally increased incidence of adenomas or squamous cell carcinomas (combined) of the clitoral gland. Under these conditions, the 2-year gavage studies in male and female rats were considered inadequate because of extensive and early mortality at the high dose or at body doses and the lack of conclusive evidence of a carcinogenic effect (125a). In female Fisher 344 rats treated with this agent to induce ovarian failure followed by application of the carcinogen dimethylbenzanthracene (DMBA) directly to the ovaries, there resulted tumors in 42% of animals at 3 months and 57% at 5 months (126b). All neoplasms were classified Sertoli–Leydig cell tumors (SLCT). No tumors occurred in animals treated with vehicle or DMBA alone.

• 輸送方法

  UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.

• 不和合性

  Vapor may form explosive mixture with air. Hydrolyzes in water. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, amines, alcohols.

• 廃棄物の処理

  Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

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