クロム酸銅

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H272：火災助長のおそれ；酸化性物質

  H335：呼吸器への刺激のおそれ

  H410：長期的影響により水生生物に非常に強い毒性

• 注意書き

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P220：衣類/．．．/可燃物から遠ざけること。

  P261：粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。

  P271：屋外または換気の良い場所でのみ使用すること。

  P273：環境への放出を避けること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

クロム酸銅 価格

クロム酸銅 化学特性,用途語,生産方法

• 説明

  Copper chromite is a black powder and inorganic pigment thatadopts a spinel crystal structure. It can be made by the high-temperaturecalcination of copper(II) oxide and chromium(III) oxide or the thermaldecomposition of copper chromate, which evolves oxygen at higher temperaturesand decomposes to copper chromite.
  
  The copper chromite (CuCr2O4) is one of the most efficient materials, has wide commercial application as catalysts being used in the unit processes of organic synthesis such as hydrogenation, dehydrogenation, hydrogenolysis, oxidation, alkylation, cyclization, etc. It can be used in the pollution abatement as the catalyst to remove aqueous organic wastes, volatile organic compound (VOC) and vehicular primary emissions such as CO, unburned hydrocarbon, NOx and soot.

• 化学的特性

  black powder

• 使用

  Copper chromite is primarily used as a catalyst forhydrogenation reactions because of its ability to hydrogenate functional groupsin aliphatic and aromatic compounds selectively. Industrially, copper chromiteis used to reduce furfural to furfuryl alcohol and butyraldehyde to 1-butanol,partially reduce conjugated dienes to monoenes, and selectively reduce carbonylgroups in vegetable oils. This CuCr catalyst is studied for a variety ofcatalytic applications including converting the hydrogenolysis of cellulose.It is also used as a catalyst for combustion to help control burn rate and as alight-absorbing pigment.

• 製造方法

  Copper chromite is produced by thermal decomposition of one of three substances. The traditional method is by the ignition of copper chromate:
  2CuCrO4 → 2CuCrO3 + O2
  Copper barium ammonium chromate is the most commonly used substance for production of copper chromite. The resulting copper chromite mixture produced by this method can only be used in procedures that contain materials inert to barium, as barium is a product of the decomposition of copper barium ammonium chromate, and is thus present in the resulting mixture. The by-product copper oxide is removed using an acetic acid extraction, consisting of washing with the acid, decantation and then heat drying of the remaining solid to yield isolated copper chromite. Copper chromite is produced by the exposure of copper barium ammonium chromate to temperatures of 350-450 °C, generally by a muffle furnace:
  Ba2Cu2(NH4)2(CrO4)5 → CrCuO3 + CuO + 2Ba + 4H2O + 4Cr + N2 + 6O2

クロム酸銅 上流と下流の製品情報

クロム酸銅 生産企業

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