Dibortrioxid

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Achtung

• Sicherheit

  P201：Vor Gebrauch besondere Anweisungen einholen.

  P202：Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.

  P280：Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

  P308+P313：BEI Exposition oder falls betroffen: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

  P405：Unter Verschluss aufbewahren.

  P501：Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Boron oxide Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  FARBLOSE, GERUCHLOSE, HYGROSKOPISCHE, SPRöDE, GLASARTIGE ODER HARTE WEISSE KRISTALLE MIT LEICHT BITTEREM GESCHMACK.

• CHEMISCHE GEFAHREN

  Reagiert langsam mit Wasser unter Bildung von Borsäure. Greift Metall in Gegenwart von feuchter Luft an.

• ARBEITSPLATZGRENZWERTE

  TLV: 10 mg/m?(als TWA); (ACGIH 2005).
  MAK: IIb (nicht festgelegt, aber Informationen vorhanden) (DFG 2008).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation des Aerosols und durch Verschlucken.

• INHALATIONSGEFAHREN

  Verdampfen bei 20°C vernachlässigbar; eine belästigende Partikelkonzentration in der Luft kann jedoch beim Dispergieren schnell erreicht werden.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Die Substanz reizt die Augen, die Haut und die Atemwege.

• LECKAGE

  Verschüttetes Material in Behältern sammeln; falls erforderlich durch Anfeuchten Staubentwicklung verhindern. Reste sorgfältig sammeln. An sicheren Ort bringen. Persönliche Schutzausrüstung: Atemschutzgerät, P1-Filter für inerte Partikel.

• R-Sätze Betriebsanweisung:

  R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

• S-Sätze Betriebsanweisung:

  S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
  S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

• Beschreibung

  Boron oxide is a noncombustible, colorless,semitransparent lumps or hard, white, odorless crystals,with slightly bitter taste. Molecular weight=69.64; Boilingpoint=about 1860℃; Freezing/Melting point=about450℃. Hazard Identification (based on NFPA-704 MRating System): Health 2, Flammability 0, Reactivity 0.Moderately soluble in water; solubility=(moderate) 3%;slow reaction.

• Chemische Eigenschaften

  Boron oxide is a noncombustible, colorless, semitransparent lumps or hard, white, odorless crystals, with slightly bitter taste.
  

• Chemische Eigenschaften

  white powder or glassy flakes

• Physikalische Eigenschaften

  Colorless glassy solid or vitreous crystal; hexagonal crystal system; slightly bitter taste; hygroscopic; density 2.55 g/cm³; melts at 450°C; vaporizes at 1,500°C; slightly soluble in cold water (3.3%), soluble in alcohol and boiling water (20%).

• Verwenden

  In preparation of fluxes; component of enamels and glass; catalyst in organic reaction

• Verwenden

  A saturated solution of H3BO3 contains about 2% of the compound at 0 C, increasing to about 39% at 100 C. The compound also is soluble in alcohol. In preparations, solutions of boric acid are nonirritating and slightly astringent with antiseptic properties. Although no longer used as a preservative for meats, boric acid finds extensive use in mouthwashes, nasal sprays, and eye-hygiene formulations. Boric acid (sometimes with borax) is used as a fire-retardant. A commercial preparation of this type (Minalith) consists of diammonium phosphate, ammonium sulfate, sodium tetraborate, and boric acid. The tanning industry uses boric acid in the deliming of skins where calcium borates, soluble in H2O, are formed. As sold commercially, boric acid is B3O3·3H2O, prepared by adding HCl or H2SO4 to a solution of borax.

• Verwenden

  Boron oxide was used as the intermediate glass layer at a bonding temperature of 450°C. In preparation of fluxes; component of enamels and glass; catalyst in organic reaction.
  In metallurgy; in analysis of silicates to determine SiO2 and alkalies; in blowpipe analysis.

• synthetische

  Boric oxide is produced by treating borax with sulfuric acid in a fusion furnace. At temperatures above 750°C, the molten boric acid layer separates out from sodium sulfate. It then is decanted, cooled, and obtained in 96-97% purity. Boric acid above 99% purity may be obtained by fusing granular material.
  Boric oxide may be prepared by heating boric acid.
  2B(OH)₃ → B2O₃ + 3H₂O

• Definition

  ChEBI: Diboron trioxide is a boron oxide with formula B2O3.

• Vorbereitung Methode

  Boric oxide is produced by thermal fusion of boric acid, forming a clear transparent glass-like solid that is subsequently ground into white vitreous granules. It is used principally in the manufacture of glass and vitreous products.

• Allgemeine Beschreibung

  Colorless, semi-transparent glassy lumps or hard white odorless crystals. Mp 450°C; bp: 1860°C. Density: 2.46 g cm-3. Moderately soluble in water. Used as an insecticide; as the starting material for the synthesis of other boron compounds; as a fluxing agent in enamels and glasses; and in mixture with 2-6% boron nitride, as a bonding agent in the hot isostatic pressing of boron nitride ceramics.

• Reaktivität anzeigen

  Boron oxide is non-combustible. Of generally low chemical reactivity. Reacts exothermically but slowly with water to form boric acid, a weak acid. Reacts exothermically with strong bases. May react with strong reducing agents such as metal hydrides, metal alkyls to generate flammable or explosive gases. May react violently on contact with bromine pentafluoride. Corrosive to metals in the presence of air.

• Hazard

  Eye and upper respiratory tract irritant.

• Health Hazard

  Boron oxide is an eye and respiratory irritant. In 113 workers exposed to boron oxide and boric acid dusts, there were statistically significant increases in symptoms of eye irrita- tion; dryness of the mouth, nose, and throat; sore throat; and productive cough compared with controls. The mean exposure level was 4.1mg/m3 , with a range of 1.2–8.5mg/m3 . Exposures may occasionally have exceeded 10 mg/m3 . Because of mixed exposures, the study does not indicate whether boron oxide or boric acid dust is more important in causing symp- toms, nor does it indicate the minimum duration of exposure necessary to produce symptoms.
  Excessive absorption of boron oxide may lead to cardiovascular collapse, alterations in temperature regulation, and coma.

• Biochem/physiol Actions

  Boric anhydride is an oxide of boron that shows antimicrobial property along with lower aminoalcohols.

• mögliche Exposition

  Boron oxide is used in glass manufacture and the production of other boron compounds. It is used in fluxes, enamels, drying agents, and as a catalyst.

• Erste Hilfe

  If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contactsthe skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately.If this chemical has been inhaled, remove fromexposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

• Lager

  Color Code—Green: General storage may be used.Store in tightly closed containers in a dry, well-ventilatedarea away from incompatible materials listed above andwater.

• Versand/Shipping

  UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9—Miscellaneous hazardous material, Technical Name Required.

• Inkompatibilitäten

  Incompatible with bromine pentafluoride, calcium oxide. Reacts slowly with water, forming boric acid. Reacts exothermically with alkaline material and strong bases. May react with strong reducing agents such as metal hydrides, metal alkyls to generate flammable or explosive gases. May react violently on contact with bromine pentafluoride. Corrosive to metals in the presence of air.

Boron oxide Upstream-Materialien And Downstream Produkte

Dibortrioxid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global(363)Suppliers

1303-86-2, Boron oxide Verwandte Suche: