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101-14-4

Name 4,4'-Methylene bis(2-chloroaniline)
CAS 101-14-4
EINECS(EC#) 202-918-9
Molecular Formula C13H12Cl2N2
MDL Number MFCD00047829
Molecular Weight 267.15
MOL File 101-14-4.mol

Chemical Properties

Appearance off-white powder
Melting point  102-107 °C(lit.)
Boiling point  202-214 °C0.3 mm Hg(lit.)
density  1.44
vapor pressure  0.001Pa at 20℃
refractive index  1.6710 (estimate)
Fp  >230 °F
solubility  Acetonitrile (Slightly), DMSO (Slightly), Methanol (Slightly)
form  neat
pka 3.33±0.25(Predicted)
color  Light orange to Yellow to Green
Stability: Stable, but decomposes exothermically, and possibly explosively, above 200 C. Incompatible with strong oxidizing agents.
Water Solubility  <0.1 g/100 mL at 25 ºC
Merck  6059
BRN  1882318
InChIKey IBOFVQJTBBUKMU-UHFFFAOYSA-N
LogP 2.5 at 25℃
CAS DataBase Reference 101-14-4(CAS DataBase Reference)
IARC 1 (Vol. Sup 7, 57, 99, 100F) 2012
NIST Chemistry Reference Aniline), methylene bis-4,4'-(2-chloro-(101-14-4)
EPA Substance Registry System 101-14-4(EPA Substance)

Safety Data

Hazard Codes  T,N
Risk Statements 
R45:May cause cancer.
R22:Harmful if swallowed.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R53:May cause long-term adverse effects in the aquatic environment.
R50:Very Toxic to aquatic organisms.
Safety Statements 
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  CY1050000
HazardClass  6.1(b)
PackingGroup  III
HS Code  29215900
Safety Profile
Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion and intraperitoneal routes. Mutation data reported. Flammable liquid. Reactive with active metals such as sodium, potassium, magnesium, or zinc. When heated to decomposition it emits very toxic fumes of Cland NOx.
Hazardous Substances Data 101-14-4(Hazardous Substances Data)
Toxicity
LD50 oral in rat: 1140mg/kg

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Hazard Information

Material Safety Data Sheet(MSDS)

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